• Volume/Page
  • Keyword
  • DOI
  • Citation
  • Advanced
   
 
 
 

Flickr Twitter UniPHY Group iResearch App Facebook

J. Appl. Phys. 110, 114902 (2011); http://dx.doi.org/10.1063/1.3663437 (10 pages)

Subharmonic excitation in amplitude modulation atomic force microscopy in the presence of adsorbed water layers

Sergio Santos1, Victor Barcons2, Albert Verdaguer3, and Matteo Chiesa1,4

1Laboratory of Energy and Nanosciences, Masdar Institute of Science and Technology, P.O. BOX 54224, Abu Dhabi, United Arab Emirates
2Departament de Disseny i Programació de Sistemes Electrònics, UPC - Universitat Politècnica de Catalunya Av. Bases, 61, 08242 Manresa, Spain
3Centre d’ Investigació en Nanociència i Nanotecnologia (CIN2) (CSIC-ICN), Esfera UAB, Campus de la UAB, Edifici CM-7, 08193-Bellaterra, Catalunya, Spain
4Department of Mechanical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139-4307, USA

View MapView Map

(Received 8 July 2011; accepted 26 October 2011; published online 2 December 2011)

In ambient conditions, nanometric water layers form on hydrophilic surfaces covering them and significantly changing their properties and characteristics. Here we report the excitation of subharmonics in amplitude modulation atomic force microscopy induced by intermittent water contacts. Our simulations show that there are several regimes of operation depending on whether there is perturbation of water layers. Single period orbitals, where subharmonics are never induced, follow only when the tip is either in permanent contact with the water layers or in pure noncontact where the water layers are never perturbed. When the water layers are perturbed subharmonic excitation increases with decreasing oscillation amplitude. We derive an analytical expression which establishes whether water perturbations compromise harmonic motion and show that the predictions are in agreement with numerical simulations. Empirical validation of our interpretation is provided by the observation of a range of values for apparent height of water layers when subharmonic excitation is predicted.

© 2011 American Institute of Physics

Article Outline

  1. INTRODUCTION
  2. MODEL AND METHODS
  3. RESULTS AND DISCUSSION
    1. The analytic expression for stability and its consequences
    2. Subharmonics and limit cycles
    3. Consequences for apparent height
  4. CONCLUSION

RELATED DATABASES

To view database links for this article, you need to log in.

KEYWORDS and PACS

PACS

  • 68.37.Ps

    Atomic force microscopy (AFM)

  • 82.53.St

    Femtochemistry of adsorbed molecules

  • 02.60.-x

    Numerical approximation and analysis

  • 03.65.Ge

    Solutions of wave equations: bound states

  • 68.08.Bc

    Wetting

ARTICLE DATA

PUBLICATION DATA

ISSN

0021-8979 (print)  
1089-7550 (online)

For access to fully linked references, you need to log in.
    C. Bustamante and D. Keller, Phys. Today 48, 33 (1995)PHTOAD000048000012000032000001.

    Y. Martin, C. C. Williams, and H. K. Wickramasinghe, J. Appl. Phys. 61, 4723 (1987)JAPIAU000061000010004723000001.

    A. L. Weisenhorn, P. Maivald, H. J. Butt, and P. K. Hansma, Phys. Rev. B 45, 11226 (1992).

    A. l. Weisenhorn, P. K. Hansma, T. R. Albrecht, and C. F. Quate, Appl. Phys. Lett. 54, 2651 (1989)APPLAB000054000026002651000001.

    F. J. Giessibl, Phys. Rev. B 56, 16010 (1997).

    J. P. Cleveland, B. Anczykowski, A. E. Schmid, and V. B. Elings, Appl. Phys, Lett. 72, 2613 (1998)APPLAB000072000020002613000001.

    M. Marth, D. Maier, and J. Honerkamp, J. Appl. Phys. 85, 7030 (1999)JAPIAU000085000010007030000001.

    L. Nony, R. Boisgard, and J. P. Aime, J. Chem. Phys. 111, 1615 (1999)JCPSA6000111000004001615000001.

    L. Zitzler, S. Herminghaus, and F. Mugele, Phys. Rev. B 66, 155436 (2002).

    R. Szoszkiewicz and E. Riedo, Phys.l Rev. Lett. 95, 135502 (2003).

    A. Verdaguer, M. Cardellach, and J. Fraxedas, J. Chem. Phys. 129, 174705 (2008)JCPSA6000129000017174705000001.

    T. R. Rodríguez and R. García, Appl. Phys. Lett. 80, 1646 (2002)APPLAB000080000009001646000001.

    S. Santos and N. H. Thomson, Appl. Phys. Lett. 98, 013101 (2011)APPLAB000098000001013101000001.

    R. Stark, G. Schitter, and A. Stemmer, Phys. Rev. B 68, 0854011 (2003).

    P. Gleyzes, P. K. Kuo, and A. C. Boccara, Appl. Phys. Lett. 58, 2989 (1991)APPLAB000058000025002989000001.

    R. Garcia and A. San Paulo, Phys. Rev. B 61, R13381 (2000).


For access to citing articles, you need to log in.


Figures (8)

Access to article objects (figures, tables, multimedia) requires a subscription; log in to view available files.
(Access to supplementary files, where available, is free for this journal.)



Close
Google Calendar
ADVERTISEMENT

close